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Books : Cosorption of zinc and glyphosate on two soils with different characteristics [An article from: Journal of Hazardous Materials]


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by: Y.J. Wang, D.M. Zhou, R.J. Sun, L. Cang, X.Z. Hao

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Binding: Digital
Format: HTML
Label: Elsevier
Manufacturer: Elsevier
Publication Date: September 01, 2006
Publisher: Elsevier
Studio: Elsevier






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Product Description:
This digital document is a journal article from Journal of Hazardous Materials, published by Elsevier in 2006. The article is delivered in HTML format and is available in your Amazon.com Media Library immediately after purchase. You can view it with any web browser.

Description:
Agricultural application of large amounts of glyphosate [N-(phosphonomethyl)-glycine] may affect soil metal behaviors to some extend, because glyphosate can react with many kinds of metals to form metal complexes. Cosorption of Zn and glyphosate on a Red soil (RS, Udic Ferrosols) and a Wushan soil (WS, Anthrosol) was studied. In comparison with the WS, the RS has less adsorption capacity for Zn and higher for glyphosate. The presence of glyphosate decreased Zn adsorption on the two soils, which are resulted from the decreased equilibrium solution pH caused by the added glyphosate, and also the formation of water-soluble complexes of glyphosate with solution Zn^2^+ that had lower affinity to soil surface in comparison with Zn^2^+ itself. Such effect is more significant on the RS than on the WS, mainly because of the less adsorption quantity of Zn on the former one. On the contrary, the presence of Zn increased the adsorption quantities of glyphosate on the RS and WS, which is resulted from the decreasing pH value of the equilibrium solution caused by Zn^2^+ exchange with H^+ ions of soil surface. Such results suggest that glyphosate in field may increase the mobility and bioavailability of Zn and correspondingly increase its environmental risk.








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